RESUMO
Direct femtosecond laser writing of ferroelectric domain structures has been an indispensable technique for engineering the second-order optical nonlinearity of materials in three dimensions. It utilizes localized thermoelectric field motivated by nonlinear absorption at the position of laser focus to manipulate domains. However, the impact of laser wavelengths, which is pivotal in nonlinear absorption, on the inverted domains is still sketchy. Herein, the light-induced ferroelectric domain inversion is experimentally studied. It is shown that the domain inversions can be achieved over a broad spectral range, but the optical threshold for domain inversion varies dramatically with the laser wavelength, which can be explained by considering the physical mechanism of femtosecond laser poling and nonlinear absorption properties of the crystal. Meanwhile, the effects of other laser processing parameters are also experimentally investigated. Our findings are useful to guide the fabrication of high-performance optical and electronic devices based on ferroelectric domains.
RESUMO
The nonlinear optical properties of emerging metal halide perovskites (MHP) materials are sufficiently intriguing that this topic has become the hotspots in the realm of material science. Hence, we investigate the third-order nonlinear optical properties of CsPbBrx/I3-x (x = 1, 2, 3) MHP nano-crystals (NCs) embedded chalcogenide glass (ChG) within a GeS2-Sb2S3 pseudo-binary system, by monitoring the composition, excitation wavelength and intensity dependencies via femtosecond Z-scan technique. We have found that the intrinsic large optical nonlinearity of ChG can be further enhanced because of the incorporation of MHP NCs, and that the optical nonlinearity of MHP-ChG containing pristine Br NCs is more pronounced compared to its counterparts with mixed Br/I NCs, due to a combination of multiple factors.
